Baker spent five years at the professional services firm working as a chartered accountant and in its transaction services division.
He also worked in a variety of UK mid-market buy-side and sell-side private equity and corporate transactions.
The firm is currently investing from its fifth fund raised in 2011, and targets investments of between €10m and €50m in each deal.
Earlier this year the firm invested £16m for a minority stake in Instant Offices.
The company had seen revenue increase by 30 per cent in 2012 to over £22m.
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